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Bromochlorobenzene

From Wikipedia, the free encyclopedia

Bromochlorobenzenes are mixed aryl halides (aryl chloride and aryl bromide) consisting bromine and chlorine as substituents on a benzene ring.

Isomers of Bromochlorobenzene
Skeletal formula
General
Common names o-bromochlorobenzene
ortho-bromochlorobenzene
m-bromochlorobenzene
meta-bromochlorobenzene
p-bromochlorobenzene
para-bromochlorobenzene
Systematic name 1-bromo-2-chlorobenzene 1-bromo-3-chlorobenzene 1-bromo-4-chlorobenzene
Molecular formula BrC6H4Cl
Molar mass 191.45 g/mol
CAS number 694-80-4 108-37-2 106-39-8
ChemSpider 12230 13875377 7518
PubChem CID 12754 7928 7806
Properties
Melting point −13 °C (260 K) −22 °C (251 K) 63–67 °C (336–340 K)
Boiling point 203–205 °C (476–478 K) 195–196 °C (468–469 K) 196 °C (469 K)

All three have been synthesized by various routes:

See also

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References

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  1. ^ Hartwell, Jonathan L. (1944). "o-Chlorobromobenzene". Organic Syntheses. 24: 22.
  2. ^ Moerlein, S. M. (1987). "Use of aryltrimethylgermanium substrates for facile aromatic chlorination, bromination, and iodination". The Journal of Organic Chemistry. 52 (4): 664–667. doi:10.1021/jo00380a031.
  3. ^ Hosomi, Akira; Iijima, Susumu; Sakurai, Hideki (1981). "Carbon–silicon bond cleavage of organotrialkoxysilanes and organosilatranes with m-chloroperbenzoic acid and N-bromosuccinimide. New route to phenols, primary alcohols and bromides". Chemistry Letters. 10 (2): 243–246. doi:10.1246/cl.1981.243.
  4. ^ Wiley, G. A.; Hershkowitz, R. L.; Rein, B. M.; Chung, B. C. (1964). "Studies in Organophosphorus Chemistry. I. Conversion of Alcohols and Phenols to Halides by Tertiary Phosphine Dihalides". Journal of the American Chemical Society. 86 (5): 964–965. doi:10.1021/ja01059a073.
  5. ^ Bay, Elliott; Bak, David A.; Timony, Peter E.; Leone-Bay, Andrea (1990). "Preparation of aryl chlorides from phenols". The Journal of Organic Chemistry. 55 (10): 3415–3417. doi:10.1021/jo00297a087.